@rranjith_kum
Hello Ranjith,
Time to fulfill your wishes
, we will take queries one by one:-
1.) NOx emissions of the Bio diesel increases with increasing concentration...
The tailpipe emissions of Diesel engines with Biodiesel blends is a very interesting subject to study. More you study, more you understand how the whole thing work. NREL (National Renewable Energy Lab, US) & NBB (National Biodiesel Board, US)has done wonderful job evaluating everything related to Biodiesel application/quality/nitty gritties.
First & foremost, download the pdf presentation attached in the reply & understand it fully.
Than I suggest that you refer to...
http://www.biodiesel.org/resources/r...101_gen382.pdf
...& then come back if you still have queries. Just to give you basic idea, Biodiesel contains less Carbon, more hydrogen & oxygen* as compared to Fossil diesel (*Fossil diesel is Hydrocarbon & no oxygen is present in the fuel itself unless some Oxygentaors are added to boost the performance of fuel). This oxygen reacts with Nitrogen present in the compressed air (remember, we studied in school about how much Nitrogen is present in the air) inside the engine during firing. By the way, more you blend Biodiesel in your fuel, more NOx emissions will be there as you be putting more oxygen in the engine.
By the way, latest research says that upto B20 on average, you dont see much difference on NOx emissions. Check
NREL study shows B20 usage doesn’t affect NOx emissions - Biodiesel Magazine
There are many ways to reduce NOx emission due to use of Biodiesel & easy one is to add additive else you have to make changes with injection system, Air/fuel ratios, compression ratios. Check
http://www.biodiesel.org/resources/r...01_gen-040.pdf
Instead of disturbing engine or expecting your car maker to do this kind of favor for you, cheaper/simpler/faster way is to add Additives. Biodiesel gives too many benefits & can easily compensate for additive cost ofcourse. That complete first point raised by you.
Now as it was your wish, I will give you some added bonus my friend. There is way through which you can convert Vegetable oil into something which is known as
Green Diesel. As explained above, Oxygen present in Biodiesel plays the role of culprit to raise NOx in Tailpipe emissions. Now think about a process which replaces that Oxygen with Hydrogen (Definitely you wont like to increase carbon, do you?? We are talking about Carbon sequestering these days so no more carbon please). The process of coverting Veg Oil into Green diesel is named as
Ecofining (TM) by the firm that commercialized it (UOP LLC, USA). Check
Ecofining for Green Diesel Fuel
Whoop, that was a long answer but then, it was a matter of your wish, right.
2.) In Europe due to strict emission norms, Diesel Particulate Filters(DPF) have almost become a standard...
I wont spend much of my weekend time on this one, here you go. quote from external link
For diesel exhaust system suppliers, the past several years have been consumed by development and fine-tuning of emission control technologies so that original equipment manufacturers (OEM) can meet very strict U.S. EPA regulations on particulate matter and nitrogen oxides (NOx). That huge body of work culminates in the 2010 production year as unprecedented design and function result in ultra-sophisticated commercial systems. Liquid urea and a storage tank, injectors, mixers, catalysts and sensors are just some of the items many aftertreatment systems utilize to convert NOx into nitrogen and water. Upstream from NOx control in many designs is a diesel particulate filter (DPF), which traps virtually all of the black soot typically associated with diesel trucks. Before the DPF, most systems have a diesel oxidation catalyst (DOC) to oxidize the hydrocarbons.
For details,read
Year of the SCR System - Biodiesel Magazine
& then read some more about Post Injection systems:
Understanding the Post-Injection Problem - Biodiesel Magazine
That is more than you need for the time being
Let us move to last query now.
3.) I always felt that usage of bio fuels meant loss in power when running in full load (typical diesel application) maybe your can share you views on this.....
Very good question. Majority of the people ask about FE but you queried about Power, I am impressed. To answer this, I suggest you refer to a very elaborate reply I gave to Rehaan's queries on 4th March in the same thread. It is not a matter of just Loss of power. There are too many factors involved with in it & it is not so simple to explain unless the whole picture of how engines work is clear. At a grass route level, try to grab some stuff on "Heat of combustion" & "Energy Content" of various fuels. Energy content is directly related to FE. Biodiesel is a very good lubricant & infact give you better performance when used with ULSD (Less sulfur means more friction). Now coming back to basic question asked, diesel engine's role is to convert the energy content present in the fuel to power. Now if an engine is designed for a particular volume of fuel going into the system than it will definitely give you less power with biodiesel since same volume (or mass) of Biodiesel on any given day will give you less energy than same volume (or mass) of fossil fuel. That is the way they are expected to behave. Ofcourse you can compensate for the loss of power when you use Biodiesel blends by tweaking Volume of Biodiesel blend injected in the engine but what impact that will cause may be answered by an engine specialist/Distinguished/Senior BHPian having far better knowledge on that aspect. One thing for sure, you start playing with these hardcore settings & you may have many consequences (Good as well bad for sure) & you may void OEM guarantees as well so be cautious before playing with you car.
I tried my best to completely answer your wishlist. Let me know if somethingis missing. I forgot to answer about cleaning effect of Biodiesel & to answer that, I will say Biodiesel is a very strong Organic solvent & have the potential to eat many of the normal rubber parts & spoil your gaskets/o-rings/other incompatible material. Once you start using Biodiesel, you are expected to clean/replace your fuel filter very soon because Biodiesel is known to flush all the junk present in your Fuel tank. One of my friend working for a World giant in Biofuel even asked me to help him with exploring Indian market for Methyl Soyate (Soy Oil Biodiesel) as organic Industrial solvent that can replace non-renewable solvents of similar specs. You might have seen mechanics cleaning the engine parts with diesel/petrol removed from your tank. Just check this time what they are doing with that same stuff if it does not get evaporated all (I am talking about large service station who produce too much of the waste solvent). Its a long subject itself so may be we can catch up sometime later with this.
Regards
Dharmesh