congrats on nearing 200K

!!
just a few quick basic suggestions from the top of my head considering age of your engine and driving style.
I'd suggest begin with a compression test - just to see how much life you have left or if there is something serious you need to address 1st.
This will give you a rough idea how much life your engine has left with existing components i.e how your valves/piston rings etc are doing so far.
Probably inspect the following also -
1] check the condition of the distributor, rotor, cap etc - replace it if necessary
2]check your tappet setting , get them adjusted, I feel you should keep it closer to the upper range e.g
if your specs are .13 to .17mm then keep it on the 0.16 mm.(Not sure what the specs are for a zen)
Atleast in my experience older engines need a bit more clearance when hot.
(Get it done
exactly w.r.t TDC, some mechanics are lazy. I insist on matching the CMP exactly for every cylinder even if the mechanic says the mark on the crank pulley nearly matches, in carb you may have to rely on probaly the marking on the crank/cam pulley marking etc since you dont have this sensor)
3]check conditions of your cam lobes, rockers - in case they are worn out too much.
4] check all belts - if they are showing signs of being cracked,frayed at edges etc. I'd suggesting changing all the belts itself seeing the age of your engine and your driving style.Atleast change the timing belt and idler pulley to be on the safe side..but seems you haver already taken car e of that.Just a query did you change the belt only ? or did you also change the idler ?
5] gearbox oil - when did you change it last ? you can change the oil if reqd.How does your gearbox/syncros feel now?
6] bearings - get your all 4 bearings checked, raise it on the overhead jack and see if you have play in the wheels, try and pull/push down on the wheels from the sides and see if you have play. Maybe also just give them a rotation with your hand and see if you can hear something ?
replace if necesary
7] Bushings - raise the car and see the underside, just check the condition of all your bushings, I'm guessing you may see some cracked/deformed/crushed bushings.
8] Shocks/Struts - not sure what suspension you have on your zen but check if you can see some signs of wetting/damp spots indicating worn out seals etc. Probably replace the entire shock/strut..
9] I was going to say injector cleaning ... but
10]Synthetic engine oil - Flush with decarboniser , probably use a fresh quantity of some cheap mineral oil ...
Replace with fresh new synthetic oil.
I really dont think replacing with synthetic engine oil will create any problems.
11] Simple stuff like spark plugs. Go for factory spec ones only.
12] Ignition timing - Get your "base ignition" timing set exactly as per factory spec.
I really
dont know what kind of a mechanical "ignition advance" mechanism the carb zen has. Probably get it checked also if it works as expected with a timing gun.
Probably in your carb system wed need to check the dwell angle also.
If you are replacing a worn out distributor I'm guessing this would take care of the dwell angle settings also.
If not then set the dwell correctly as per spec.
(If it was an ECU based system things would be diff, we'd disconnect the ECU for doing the base ignition and leave the advance to the ECU and its sensors etc, we dont have to worry about dwell angle

)
13] Alternator : <Post edited you already took care of it>
Cant think of more stuff at the moment, will add if I think I've missed out something.