Quote:
Originally Posted by jat There is a loss of oil through tank breathing and those vapours in the air are highly combustible and hence you are not suppose to smoke, use mobile etc near the pumps (there is a basic safety distance depending to tank construction, venting etc - but nobody follows that in India) |
Please bear with me as I answer a few important points:
True losses can result from a number of mechanisms namely:
1. Incomplete emptying,
2. Spillage,
3. Pilferage (theft),
4. Leakage,
5. Vapour loss on transfer, and
6. Breathing losses from storage tanks.
Vapour losses on transfer arise from two sources,
A. Loss of vapour in the ullage space and
B. Outgassing of volatile components during the transfer.
(Note: Ullage Space is the space between the top of your tank and the level of the fuel in your tank.)
A.
Vapour loss from the ullage space arises when the mixture of air and fuel in the ullage space in any tank is displaced by the incoming liquid fuel.
Subsequently, as the fuel is used, fresh air is drawn into the tank to replace the volume of the fuel withdrawn. The fuel then evaporates from the bulk liquid in the tank until the air in the ullage space reaches saturation.
The mechanism occurs:
1. When fuel is put into terminal storage and dispensed to the tanker,
2. When fuel is put into the tanker and discharged to the retail tanks,
3. When it is loaded into the retail tanks and dispensed to the motorist, and finally
4. When the vehicle tank is filled and fuel pumped to the engine.
Past practice was for the air/vapour mixture to be expelled to the atmosphere via the tank vent and the fuel was therefore lost to the environment. With modern petrol engine burning about 98% of the fuel entering the cylinders and with catalytic converters processing about 75% of unburnt fuel leaving the engine, total emissions from the engine exhaust represent only about 0.5% of fuel usage. Vapour losses from ullage spaces are likely to be of the order of 0.15-0.2% at each of the stages listed above and the fuel supply chain emissions are therefore comparable with vehicle operating emissions. This has led to the progressive introduction of vapour recovery technology starting at the refinery end of the supply chain. Current, vapour recovery, practice at the retail filling station is to draw the air/vapour mixture into the ullage space on the tanker to avoid the discharge to the environment. As a result the retailer should incur a similar loss as previously and the fuel supplier is left to dispose of the vapour in a less harmful way. The methods of disposal permitted depend on the size of the depot with some sites being allowed to flare the mixture, to release carbon dioxide and water vapour instead of more damaging hydrocarbons, while others are required to recover the vapour back to the refinery process.The amount of fuel lost as ullage space vapour depends on the vapour pressure of the fuel.
Losses of diesel will be insignificant due to the very low vapour pressure; losses of petrol will depend on the temperature of the ullage space and on the volatility of the fuel, which varies with the season of the year to meet the conflicting requirements for cold starting and vapour lock in the vehicle fuel system.
B.
Outgassing of volatile components. As already mentioned, liquid hydrocarbon fuels are complex mixtures of many components. In the case of petrol these components will include volatile components such as butane and pentane. These components, included to satisfy vehicle cold starting requirements, will evaporate readily and may even come out of solution to form vapour bubbles in the transfer pipes as pressure in the liquid falls below the effective vapour pressure. Pressure drops will occur whenever a liquid flows; pressures in the filling pipe are therefore lower than in the supply tank. Any bubbles formed will re-condense when the liquid pressure rises again as it comes to rest in the storage tank. If, however, they are able to rise to the surface before re-condensing they will be released as vapour to the ullage space and expelled with the normal ullage air/vapour mixture as already discussed.
The outgassing process results in the air/vapour mixture expelled from the tanks being super-saturated with vapour and as a result condensation will occur.
This can happen intwo ways:
1. A fog can form in the air stream and fine droplets will then move with the air into the tanker or out to atmosphere, or
2. Droplets of condensate can form on the pipe walls.
In the case of a fixed vent stack condensation forming on the pipe walls will ultimately drain back into the tank or evaporate into the air drawn into the tank during retail dispensing. In the case of a tanker vapour recovery system, the normal practice is to elevate the lines at the end of the filling process to drain any condensate back into the retail tanks. The extent of any condensation process will depend on the temperature of the pipe walls relative to the saturation temperature of the air /vapour mixture. As outgassing is a volatility phenomenon it will only occur with petrol and is strongly dependent on the temperature, which controls the vapour pressure.
The potential for outgassing has always existed but it increases with liquid velocity in the transfer pipes. Changes in practice with the introduction of vapour recovery systems may therefore have an influence as vapour recovery lines to tankers are generally larger than tank vent lines and so present less resistance to flow of vapour, reducing static pressure and hence potentially increasing vapour concentration. Seasonal changes in volatility will also impact on the occurrence of this loss mechanism. Where liquid is stored under pressure it has the potential to hold higher concentrations of volatile components in solution and so will have a higher vapour pressure. Such fuel would be more prone to outgassing problems.
Breathing losses from storage tanks: In normal operation the vent pipe on a tank will serve only to admit air to replace the volume of liquid dispensed to the motorist. However, under some conditions, the gas in the ullage space may expand and some will be expelled through the vent and released to atmosphere.The principal cause of this will be a reduction in atmospheric pressure when ullage gas will be vented to equalize the pressures in the tank and at the vent. The expelled gas will take with it a proportion of the vapour in the tank. This vapour will disperse and, when the atmospheric pressure rises again, pure air will be drawn into the tank allowing additional evaporation from the bulk liquid.
Wind blowing across the vent pipe will also generate a low pressure at the vent, creating a mechanism similar to atmospheric pressure changes with vapour being lost when the windblows and air drawn in when the wind drops.
Changes in temperature will create the same effect as the ullage gases expand and contract.These breathing losses can therefore be seen to be dependent on the site exposure, but at most sites are likely to be substantially less than the vapour losses incurred in tank filling. Being vapour losses, they occur only with petrol and are dependent on the storage temperature.